Solar absorption spectroscopy in the near infrared has been performed in
Ny-Ålesund (78.9° N, 11.9° E) since 2002; however, due
to the high latitude of the site, the sun is below the horizon from October
to March (polar night) and no solar absorption measurements are possible.
Here we present a novel method of retrieving the total column dry-air mole
fractions (DMFs) of CO2 and CH4 using moonlight in winter.
Measurements have been taken during the polar nights from 2012 to 2016 and
are validated with TCCON (Total Carbon Column Observing Network) measurements
by solar and lunar absorption measurements on consecutive days and nights
during spring and autumn. The complete seasonal cycle of the DMFs of
CO2 and CH4 is presented and a precision of up to 0.5 %
is achieved. A comparison of solar and lunar measurements on consecutive days
during day and night in March 2013 yields non-significant biases of 0. 66 ± 4. 56 ppm for xCO2 and −1. 94 ± 20. 63 ppb for
xCH4. Additionally a model comparison has been performed with data
from various reanalysis models.