low-temperature ozone decomposition by complexes of cu(ii), co(ii) and mn(ii) with hexamethylenetetramine
;A. S. Truba
Nature communications2016Vol. 14pp. 88-94
134
truba2016vsniklow-temperature
Abstract
First, the complexes MCl2*HTMA*xH2O/SiO2 (M = Cu(II), Co(II), Mn(II)) with hexa-methylenetetramine (HMTA) molecule weakly bound with a central M atom (CM ranging from 5.010-7 to 5.010-6 mol/g) have been found to catalyse the ozone decomposition. Their activity and turnover number exceeded much those for MCl2*хН2О/ SiO2 acido complexes