redetermination of nickel(ii) formate dihydrate

redetermination of nickel(ii) formate dihydrate

;Matthias Weil
lecture notes in civil engineering 2018 Vol. 3 pp. x180428-
243
weil2018iucrdataredetermination

Abstract

In comparison with the previous structure determination of poly[diaquadi-μ-formato-nickel(II)], [Ni(HCOO)2(H2O)2]n, based on Weissenberg film data [Krogmann & Mattes (1963). Z. Kristallogr. 118, 291–302], the current redetermination from modern CCD data revealed the positions of the H atoms, thus making a detailed description of the hydrogen-bonding pattern possible. Both Ni2+ cations in the crystal structure are located on inversion centres and are octahedrally coordinated. One Ni2+ cation is bound to six O atoms of six formate anions whereas the other Ni2+ cation is bound to four O atoms of water molecules and to two formate O atoms. In this way, the formate anions bridge the two types of Ni2+ cations into a three-dimensional framework. O—H...O hydrogen bonds of medium strength between water molecules and formate O atoms consolidate the packing.

Citation

ID: 136008
Ref Key: weil2018iucrdataredetermination
Use this key to autocite in SciMatic or Thesis Manager

References

Blockchain Verification

Account:
NFT Contract Address:
0x95644003c57E6F55A65596E3D9Eac6813e3566dA
Article ID:
136008
Unique Identifier:
10.1107/S2414314618004285
Network:
Scimatic Chain (ID: 481)
Loading...
Blockchain Readiness Checklist
Authors
Abstract
Journal Name
Year
Title
5/5
Creates 1,000,000 NFT tokens for this article
Token Features:
  • ERC-1155 Standard NFT
  • 1 Million Supply per Article
  • Transferable via MetaMask
  • Permanent Blockchain Record
Blockchain QR Code
Scan with Saymatik Web3.0 Wallet

Saymatik Web3.0 Wallet