The original and comprehensive research of Yakov Ilich Frenkel in physics and physical chemistry of condensed states, nuclear physics, electrodynamics, science of sintering has significantly contributed to the development of modern scientific knowledge and his scientific ideas are still an inspiration to many scientists. Having in mind the wealth of scientific ideas he had in the research of electroconductivity in metals, crystal structure imperfections and phase transitions and in founding the science of sintering, the contribution of individual theories of Frenkel of significance to materials science are presented in this paper.