It was established the dependence of the electrocatalytic activity of alloys Ni-Cr-Mn at the variable contents of copper with values of Fermy energy of their components. Electrocatalytic activity of alloys was estimated by density of the current, determined by the method of suspended half-element. For Fermi energy calculation of various metals Sommerfeld model, in which distribution of electrons by speed is described by Fermi-Dirac statistic was used.