A designer ligand field for blue-green luminescence of organoeuropium(II) sandwich complexes with cyclononatetraenyl ligands
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A designer ligand field for blue-green luminescence of organoeuropium(II) sandwich complexes with cyclononatetraenyl ligands

Kenshiro Kawasaki;Kenshiro Kawasaki;Rion Sugiyama;Rion Sugiyama;Takashi Tsuji;Takashi Tsuji;Takeshi Iwasa;Takeshi Iwasa;Hironori Tsunoyama;Hironori Tsunoyama;Yoshiyuki Mizuhata;Yoshiyuki Mizuhata;Norihiro Tokitoh;Norihiro Tokitoh;Atsushi Nakajima;Atsushi Nakajima;
chemical communications 2017 Vol. 53 pp. 6557-6560
130
kawasaki2017chemicala

Abstract

A novel η9-coordinated double-decker sandwich complex of divalent europium is synthesized. The complex exhibits blue-green photoluminescence at 516 nm, which is significantly blue-shifted from those of other organoeuropium(ii) sandwich complexes (∼630 nm). The blue-shift was quantitatively explained by the w

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DOI:
10.1039/C7CC03045B
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https://dx.doi.org/10.1039/C7CC03045B

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