Facile construction of uniform ultramicropores in porous carbon for advanced sodium-ion battery.

Facile construction of uniform ultramicropores in porous carbon for advanced sodium-ion battery.

Yu, Peifeng;Zhang, Weicai;Yang, Yinghan;Zheng, Mingtao;Hu, Hang;Xiao, Yong;Liu, Yingliang;Liang, Yeru;
Journal of colloid and interface science 2020 Vol. 582 pp. 852-858
133
yu2020facilejournal

Abstract

Facile fabrication of anode materials with low cost, good rate capability and high capacity is a critical factor towards developing sodium-ion battery for practical applications. Herein, a N, O co-doped porous carbon with uniform ultramicropores (NOPC-UM), is synthesized by an in-situ ultramicro templating strategy, and demonstrated as a high-performance sodium-ion storage material. Key to this strategy is employment of an inherent KCl as untramicro template, which leads to formation of uniform size of ultramicropores and heteroatoms (i.e., N and O) doping after high-temperature pyrolysis. The as-constructed NOPC-UM delivers a large capacity of 305 mAh g, accompanying with a 93% specific capacity below 1.00 V, and superior cycling stability about 100% after 4000 cycles. These attractive electrochemical performances endow NOPC-UM with impressive potential use as anode materials of sodium-ion battery.

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