A study of magnetite at 4.2 K and subject to strong applied magnetic fields

A study of magnetite at 4.2 K and subject to strong applied magnetic fields

Harker, S. J.;Pollard, R. J.;Harker, S. J.;Pollard, R. J.;
nimpb 1970 Vol. 76 pp. 61-63
125
j.1970nimpba

Abstract

Mössbauer spectra of a powdered sample of magnetite were taken at 4.2 K and in applied fields of 0-14 T. They were fitted in accordance with specific crystallographic models of magnetite below the Verwey transition. At least five octahedral Fe 3+ sites and four octahedral Fe 2+ sites are needed to obtain both good fits and parameters which vary consistently with applied field strength. The Fe 2+ ions exhibit a large quadrupole interaction, which leads to an applied-field subspectrum of unusual shape. This shape is adequately represented by an analytic calculation for a randomly oriented electric field gradient and for magnetic moments which are collinear with the applied field.

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doi:10.1016/0168-583X(93)95132-O
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