The effect of photocatalyst excited state lifetime on the rate of photoredox catalysis

The effect of photocatalyst excited state lifetime on the rate of photoredox catalysis

J. R. Ochola;J. R. Ochola;M. O. Wolf;M. O. Wolf;
Organic & biomolecular chemistry 2016 Vol. 14 pp. 9088-9092
258
ochola2016organicthe

Abstract

Four different iridium(iii) polypyridyl complexes with varying excited state lifetimes are used as photocatalysts to study the effect of excited state lifetime on the rate of a prototypical photoredox-catalyzed reaction, the trifluoromethylation of quinoline. An improved mechanistic understanding of the phot

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118033
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10.1039/C6OB01717G
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