First use of a divalent lanthanide for visible-light-promoted photoredox catalysis
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First use of a divalent lanthanide for visible-light-promoted photoredox catalysis

Tyler C. Jenks;Tyler C. Jenks;Matthew D. Bailey;Matthew D. Bailey;Jessica L. Hovey;Jessica L. Hovey;Shanilke Fernando;Shanilke Fernando;Gihan Basnayake;Gihan Basnayake;Michael E. Cross;Michael E. Cross;Wen Li;Wen Li;Matthew J. Allen;Matthew J. Allen;
Chemical science 2018 Vol. 9 pp. 1273-1278
227
jenks2018chemicalfirst

Abstract

We report the first catalytic use of a divalent lanthanide in visible-light-promoted bond-forming reactions. Our new precatalyst uses europium in the +2 oxidation state and is active in the presence of blue light from light-emitting diodes. The use of low-energy visible light reduces the occurrence of potent

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DOI:
10.1039/C7SC02479G
URL:
https://dx.doi.org/10.1039/C7SC02479G

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