Thermal and Photochemical Reduction and Functionalization Chemistry of the Uranyl Dication, [U VI O 2] 2

Thermal and Photochemical Reduction and Functionalization Chemistry of the Uranyl Dication, [U VI O 2] 2

Cowie BE;Purkis JM;Austin J;Love JB;Arnold PL;;
chemical reviews 2019 Vol. 119 pp. -
144
be2019chemicalthermal

Abstract

The uranyl ion, [UVIO2]2+, possesses rigorously trans, strongly covalent, and chemically robust U-oxo groups. However, through the use of anaerobic reaction techniques, both one- and two-electron reductive functionalization of the uranyl oxo groups has been di …

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