This study deals with the numerical solution of the non-linear differential equations (DEs) arising in the study of hydrodynamics and hydro-magnetic stability problems using a new cubic B-spline scheme (CBS). The main idea is that we have modified the boundary value problems (BVPs) to produce a new system of linear equations. The algorithm developed here is not only for the approximation solutions of the 10th order BVPs but also estimate from 1st derivative to 10th derivative of the exact solution as well. Some examples are illustrated to show the feasibility and competence of the proposed scheme.