Calix[4]resorcinarene-based [Co] coordination cages mediated by isomorphous auxiliary ligands for enhanced proton conduction.
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Calix[4]resorcinarene-based [Co] coordination cages mediated by isomorphous auxiliary ligands for enhanced proton conduction.

Guo, Ting-Ting;Cheng, Dong-Ming;Yang, Jin;Xu, Xianxiu;Ma, Jian-Fang;
Chemical communications (Cambridge, England) 2019 Vol. 55 pp. 6277-6280
236
guo2019calix4resorcinarenebasedchemical

Abstract

We herein propose a design assembly of calix[4]resorcinarene-based proton-conductive [Co16] coordination cages (1-SO3H and 1-OH) by carefully mediating the acidic sites of isomorphous auxiliary ligands. Markedly, 1-SO3H exhibits a proton conductivity that increased about 1 order of magnitude relative to its counterpart 1-OH, reaching 1.35 × 10-2 S cm-1 at 90 °C and under 98% relative humidity.

Keywords

Raman Spectroscopy supramolecular self-assembly halogen bonding resorcinarene reversible addition fragmentation chain transfer polymerization

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DOI:
10.1039/c9cc01828j

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ID: 76715
Ref Key: guo2019calix4resorcinarenebasedchemical
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