Stereoselective olefin cyclopropanation under aerobic conditions with an artificial enzyme incorporating an iron-chlorin e6 cofactor
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Stereoselective olefin cyclopropanation under aerobic conditions with an artificial enzyme incorporating an iron-chlorin e6 cofactor

Sreenilayam G;Moore EJ;Steck V;Fasan R;;
ACS catalysis 2017 Vol. 7 pp. -
147
g2017acsstereoselective

Abstract

Myoglobin has recently emerged as a promising biocatalyst for catalyzing carbene-mediated cyclopropanation, a synthetically valuable transformation not found in nature. Having naturally evolved for binding dioxygen, the carbene transferase activity of this metalloprotein is severely inhibited by it, …

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National Center for Biotechnology Information NCBI NLM MEDLINE pubmed abstract nih national institutes of health national library of medicine pmid:29576911 pmc5863724 doi:10.1021/acscatal.7b02583 gopeekrishnan sreenilayam eric j moore rudi fasan

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