Stereoselective olefin cyclopropanation under aerobic conditions with an artificial enzyme incorporating an iron-chlorin e6 cofactor
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Stereoselective olefin cyclopropanation under aerobic conditions with an artificial enzyme incorporating an iron-chlorin e6 cofactor

Gopeekrishnan Sreenilayam, Eric J. Moore, Viktoria Steck, Rudi Fasan;Gopeekrishnan Sreenilayam;Eric J. Moore;Viktoria Steck;Rudi Fasan;
ACS catalysis 2017 Vol. 7 pp. 7629-
148
fasan2017acsstereoselective

Abstract

Myoglobin has recently emerged as a promising biocatalyst for catalyzing carbene-mediated cyclopropanation, a synthetically valuable transformation not found in nature. Having naturally evolved for binding dioxygen, the carbene transferase activity of ...

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DOI:
10.1021/acscatal.7b02583
URL:
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC586372...

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