Reproducible Dry Stamping Transfer of PEDOT:PSS Transparent Top Electrode for Flexible Semi-transparent Metal Halide Perovskite Solar Cells.
Lee, Jong Hwa;Heo, Jin Hyuck;Im, Sang Hyuk;Park, O Ok;
ACS applied materials & interfaces2020
317
lee2020reproducibleacs
Abstract
A semi-transparent flexible metal halide perovskite (MHP) solar cells were demonstrated by reproducible dry stamping transfer of a poly(3,4-ethylenedioxythiophene):poly(styrene sulfonic acid) (PEDOT:PSS, PH1000) transparent flexible top-electrode onto a poly(ethylene terephthalate) (PET)/ITO/PEDOT:PSS (AI4083)/MHP/[6,6]-phenyl-C61-butyric acid methyl ester (PCBM). The reproducible transfer of the PEDOT:PSS top electrode was enabled by the modification of PEDOT:PSS with poly(ethylene imine) (PEI)/2-methoxyethanol (2-MEA) solution. In addition, the PEI/2-MEA modification to PEDOT:PSS resulted in the improved conductivity and the reduced work function of top electrode. Therefore, we could fabricate highly efficient flexible semi-transparent MHP solar cells with > 13 % (active area = 1 cm2) of power conversion efficiency.