The aim of this study was to identify the influences of psychological capital (PC) on students' entrepreneurial intention (EI) in China's universities. The mediating effects of Entrepreneurial Capitals were also examined. Based on the analysis of the traditional capital and PC, the paper proposes that traditional capital is the direct factor to drive the behavior of entrepreneurship, while psychological factors do not directly affect EI, but improve EI by influencing traditional capital. A total of 1914 responses from universities in southeast China were analyzed using the structural equation modeling (SEM) approach to test study hypotheses. Results show that PC has a significant indirect impact on students' EI only through traditional financial, human, and social capital (SC). These results support the mediating role of the traditional entrepreneurial capitals in explaining the relationship between PC and EI. Additionally, the impact of SC on EI is higher than that of financial and human capital (HC). Finally, research limitations and implications are discussed and future research directions are suggested.