Nickel(ii)-methyl complexes adopting unusual seesaw geometries.
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Nickel(ii)-methyl complexes adopting unusual seesaw geometries.

Hill, Ethan A;Zhao, Norman;Filatov, Alexander S;Anderson, John S;
Chemical communications (Cambridge, England) 2020
187
hill2020nickeliimethylchemical

Abstract

We report four-coordinate nickel(ii)-methyl complexes of tris-carbene borate ligands which adopt rare seesaw geometries. Experimental and computational results suggest the structural distortion from threefold symmetry results from a combination of electronic stabilization of the singlet state, strong field donors, and constrained angles from the chelating ligand.

Keywords

amine-imine-exchange strategy morphological transformation orthogonal dynamic covalent self-assembly polymer nanocapsules and thin films

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DOI:
10.1039/c9cc09249h

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ID: 92625
Ref Key: hill2020nickeliimethylchemical
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92625
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10.1039/c9cc09249h
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