Conversion inorganic interlayer of a LiF/graphene composite in all-solid-state lithium batteries.

Conversion inorganic interlayer of a LiF/graphene composite in all-solid-state lithium batteries.

Li, Yingxiang;Li, Yiqiu;Yang, Yanan;Cui, Zhonghui;Wang, Jiacheng;Zhang, Tao;
Chemical communications (Cambridge, England) 2020
192
li2020conversionchemical

Abstract

The issues at the interface between the solid-state electrolyte (SSE) and electrodes limit the development of all-solid-state lithium batteries (ASSLBs). Herein, we report a LiF/graphene inorganic composite interlayer (ICI) which is in situ constructed at the cathode/garnet interface by electrochemical pre-lithiation of fluorinated graphene (GF). The ICI with flexibility and ion-conductivity can improve the contact between the cathode and garnet electrolyte, and thus enables the ASSLB to stably operate for 60 cycles without any liquid conditions.

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ID: 82728
Ref Key: li2020conversionchemical
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82728
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10.1039/c9cc09318d
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