Enhanced stability in rigid peptide-based porous materials.
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Enhanced stability in rigid peptide-based porous materials.

Martí-Gastaldo, Carlos;Warren, John E;Stylianou, Kyriakos C;Flack, Natasha L O;Rosseinsky, Matthew J;
angewandte chemie (international ed in english) 2012 Vol. 51 pp. 11044-8
283
martí-gastaldo2012enhanced

Abstract

Pepped up: Notwithstanding the intrinsic conformational flexibility of peptides, [Zn(Gly-Thr)(2)] behaves as a robust porous metal-organic framework thanks to the rigidity introduced by the use of Gly-Thr (see scheme). This rigidity arises from the sequence of amino acids in the dipeptide that locks its conformational flexibility in the framework.

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DOI:
10.1002/anie.201203929

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