Broadband SERS detection with disordered plasmonic hybrid aggregates.

Broadband SERS detection with disordered plasmonic hybrid aggregates.

Mao, Peng;Liu, Changxu;Chen, Qiang;Han, Min;Maier, Stefan A;Zhang, Shuang;
Nanoscale 2019
220
mao2019broadbandnanoscale

Abstract

Plasmonic nanostructures possessing broadband intense field enhancement over a large area are highly desirable for nanophotonic and plasmonic device applications. In this study, 3D Ag hybrid nanoaggregates (3D-Ag-HNAs) are achieved via a highly efficient oblique angle gas-phase cluster beam deposition method. Not only can such structures produce a high density of plasmonic hot-spots to improve Raman sensitivity, but more importantly they generate kissing point-geometric singularities with a broadband optical response. We succeed in obtaining an experimental SERS enhancement factor beyond 4 × 107 in the visible range, providing an optimal sensing platform for different analytes. Combined with good uniformity, reproducibility and ease of fabrication, our 3D-Ag-HNA offers a candidate for new generations of SERS systems.

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66499
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10.1039/c9nr08118f
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