1,2,3-Triazolium macrocycles in supramolecular chemistry.

1,2,3-Triazolium macrocycles in supramolecular chemistry.

Safarnejad Shad, Mastaneh;Santhini, Pulikkal Veettil;Dehaen, Wim;
Beilstein journal of organic chemistry 2019 Vol. 15 pp. 2142-2155
320
safarnejad-shad2019123triazoliumbeilstein

Abstract

In this short review, we describe different pathways for synthesizing 1,2,3-triazolium macrocycles and focus on their application in different areas of supramolecular chemistry. The synthesis is mostly relying on the well-known "click reaction" (CuAAC) leading to 1,4-disubstituted 1,2,3-triazoles that then can be quaternized. Applications of triazolium macrocycles thus prepared include receptors for molecular recognition of anionic species, pH sensors, mechanically interlocked molecules, molecular machines, and molecular reactors.

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