Amine compounds are considered highly important in environmental pollution, industrial, and medicinal fields. The objective of this work was to develop a disposable, highly accurate, highly selective, and low-cost paper-based probe through the combination of color change of seven pH indicators for the detection of amine compounds in the gaseous state. The probe was designed with seven rings which were printed using the wax-printing technique and colored with different pH indicators. The colors of the probe were analyzed using red, green, and blue () values extracted from the images obtained with a homemade smartphone application. The chemometric tools, principal component analysis, and hierarchical cluster analysis methods were adapted to further classify amine gases. The colorimetric probe showed an excellent capability for detecting the amines with high accuracy, prompt response, and high selectivity. These dye arrays have been proven to detect ethanolamine (NHCHCHOH), dimethylamine ((CH)NH), and trimethylamine ((CH)N) gases at parts per million scale.