Enantioselective catalysis with a chiral, phosphane-containing PMO material

Enantioselective catalysis with a chiral, phosphane-containing PMO material

Seki T;McEleney K;Crudden CM;;
Chemical communications (Cambridge, England) 2012 pp. -
81
t2012chemicalenantioselective

Abstract

A novel bistriethoxysilyl-BINAP monomer was prepared and co-condensed with a biphenylene-bridged siloxane precursor in the presence of surfactant templates to give periodic mesoporous organosilicas (PMOs) functionalized with BINAP. Complexation of ruthenium followed by asymmetric catalytic hydrogena …

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