Enantioselective catalysis with a chiral, phosphane-containing PMO material
Seki T;McEleney K;Crudden CM;;
Chemical communications (Cambridge, England)2012pp. -
81
t2012chemicalenantioselective
Abstract
A novel bistriethoxysilyl-BINAP monomer was prepared and co-condensed with a biphenylene-bridged siloxane precursor in the presence of surfactant templates to give periodic mesoporous organosilicas (PMOs) functionalized with BINAP. Complexation of ruthenium followed by asymmetric catalytic hydrogena …