A powder neutron diffraction study of cation ordering in 6H Ba3Sb2NiO9
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A powder neutron diffraction study of cation ordering in 6H Ba3Sb2NiO9

A.J. Jacobson,A.J. Calvert;A.J. Jacobson;A.J. Calvert;
Journal of Inorganic and Nuclear Chemistry 1978 Vol. 40 pp. 447-449
198
calvert1978journala

Abstract

The structure of 6H Ba3Sb2NiO9 has been determined by profile analysis of powder neutron diffraction data. The antimony atoms occupy the pair of face-shared octahedra and the nickel is confined to the corner sharing octahedron. The unfavorable SbSb repulsion is compensated by atom displacements from ideal positions.

Keywords

structure octahedron antimony neutron diffraction powder neutron ba3sb2nio9 corner

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DOI:
10.1016/0022-1902(78)80421-7
URL:
https://sciprofiles.com/publication/view/69af7c9be...

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ID: 270059
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