Reactions of co-ordinated ligands. Part 25. The synthesis of µ-allene-dicarbonylbis(η5-indenyl)dirhodium and protonation to form a bridged cationic vinyl complex; molecular structures of µ-allene-dicarbonylbis(η5-indenyl)dirhodium and dicarbonyl-bis(η5-indenyl)-µ-(1-methylvinyl)-dirhodium(Rh–Rh) tetrafluoroborate
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Reactions of co-ordinated ligands. Part 25. The synthesis of µ-allene-dicarbonylbis(η5-indenyl)dirhodium and protonation to form a bridged cationic vinyl complex; molecular structures of µ-allene-dicarbonylbis(η5-indenyl)dirhodium and dicarbonyl-bis(η5-indenyl)-µ-(1-methylvinyl)-dirhodium(Rh–Rh) tetrafluoroborate

Yassin N. Al-Obaidi;Yassin N. Al-Obaidi;Paul K. Baker;Paul K. Baker;Michael Green;Michael Green;Nicholas D. White;Nicholas D. White;Graham E. Taylor;Graham E. Taylor;
journal of the chemical society, dalton transactions 1981 pp. 2321-2327
158
al-obaidi1981journalreactions

Abstract

Reaction (60 °C) of tri-µ-carbonyl-tris(η-indenyl)--trirhodium with allene in toluene as solvent affords µ-allene-(dicarbonyl)bis(η-indenyl)dirhodium. An -ray crystallographic study was carried out on this complex. Crystals are triclinic, space group [[1 with combining macron]] , in a unit cell of dimensions =...

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DOI:
10.1039/DT9810002321
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https://doi.org/10.1039/dt9810002321

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