Enantioselective catalysis with a chiral, phosphane-containing PMO material
Tomohiro Seki;Tomohiro Seki;Kevin McEleney;Kevin McEleney;Cathleen M. Crudden;Cathleen M. Crudden;
chemical communications2012Vol. 48pp. 6369-6371
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seki2012chemicalenantioselective
Abstract
A novel bistriethoxysilyl-BINAP monomer was prepared and co-condensed with a biphenylene-bridged siloxane precursor in the presence of surfactant templates to give periodic mesoporous organosilicas (PMOs) functionalized with BINAP. Complexation of ruthenium followed by asymmetric catalytic hydrogenation and
Chirality