2-(2-Hydroxy-3-methoxyphenyl)-1H-benzimidazol-3-ium perchlorate

2-(2-Hydroxy-3-methoxyphenyl)-1H-benzimidazol-3-ium perchlorate

Chen, Chuan;Li, Hong-Xing;Hou, Guang-Feng;Li, Guang-Ming;
acta crystallographica section e 2012 Vol. 68 pp. o1920-o1920
117
chen201222hydroxy3methoxyphenyl1hbenzimidazol3iumacta

Abstract

In the title molecular salt, C14H13N2O2+·ClO4−, the ring systems in the cation are almost coplanar [dihedral angle = 5.53 (13)°]. Intramolecular N—H...O and O—H...O hydrogen bonds generate S(6) and S(5) rings, respectively. In the crystal, the two H atoms involved in the intramolecular hydrogen bonds also participate in intermolecular links to acceptor O atoms of the perchlorate anions. A simple intermolecular N—H...O bond also occurs. Together, these form a double-chain structure along [101].

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