Hydrogen evolution from water catalyzed by cobalt-mimochrome VI*a, a synthetic mini-protein

Hydrogen evolution from water catalyzed by cobalt-mimochrome VI*a, a synthetic mini-protein

Firpo V;Le JM;Pavone V;Lombardi A;Bren KL;;
Chemical science 2018 Vol. 9 pp. -
148
v2018chemicalhydrogen

Abstract

A synthetic enzyme is reported that electrocatalytically reduces protons to hydrogen (H2) in water near neutral pH under aerobic conditions. Cobalt mimochrome VI*a (CoMC6*a) is a mini-protein with a cobalt deuteroporphyrin active site within a scaffold of two synthetic peptides covalently …

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