Direct Synthesis of ESBO Derivatives-18O Labelled with Dioxirane

Direct Synthesis of ESBO Derivatives-18O Labelled with Dioxirane

Tegola, Stefano La;Annese, Cosimo;Suman, Michele;Tommasi, Immacolata;Fusco, Caterina;D'Accolti, Lucia;
the scientific world journal 2013 Vol. 2013 pp. -
85
tegola2013directthe

Abstract

This work addresses a new approach developed in our laboratory, consisting in the application of isolated dimethyldioxirane (DDO, 1a) labelled with 18O for synthesis of epoxidized glyceryl linoleate (Gly-LLL, 2). We expect that this work could contribute in improving analytical methods for the determination of epoxidized soybean oil (ESBO) in complex food matrices by adopting an 18O-labelled-epoxidized triacylglycerol as an internal standard.

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