scattering from ramified polymeric systems

scattering from ramified polymeric systems

;M.Benhamou;N.Ghaouar;A.Gharbi;M.Benmouna
conference on human factors in computing systems - proceedings 2004 Vol. 7 pp. 179-198
215
m.benhamou2004condensedscattering

Abstract

Here, of great interest to us is a quantitative study of the scattering properties from ramified polymeric systems of arbitrary topology. We consider three types of systems, namely ramified polymers in solution, ramified polymer blends, or ternary mixtures made of two ramified polymers of different chemical nature immersed in a good solvent. To achieve the goal of the study, use is made of the Random Phase Approximation. First we determine the exact expression of the form factor of an ideal ramified polymer of any topology, from which we extract the exact expression of its gyration radius. Using the classical Zimm's formulae and the exact form factor, we determine all scattering properties of these three types of ramified polymeric systems. The main conclusion is that ramification of the chains induces drastic changes of the scattering properties.

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213142
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