utilization of zinc dust for a core monomer 2-bromo-3-hexylthien-5-ylzinc bromide: its synthesis and application for the preparation of regioregular poly(3-hexylthiophene)
Abstract
The oxidative insertion of readily available zinc dust into the carbon-bromine bond of 2,5-dibromo-3-hexylthiophene was efficiently achieved to provide 2-bromo-3-hexylthien-5-ylzinc bromide (I), which was utilized for the preparation of highly regioregular poly(3-hexylthiophene) (P3HT) in the presence of catalytic amounts of Ni-catalyst.
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208219
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0x95644003c57E6F55A65596E3D9Eac6813e3566dA
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208219
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10.1155/2014/847309
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Scimatic Chain (ID: 481)
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