thomson's formulation of the second law for macroscopic and finite work sources
;Theo M. Nieuwenhuizen;Roger Balian;Armen E. Allahverdyan
European journal of medicinal chemistry2004Vol. 6pp. 30-37
234
nieuwenhuizen2004entropythomson's
Abstract
Abstract: Thomson's formulation of the second law states: no work can be extracted from an equilibrium system through a cyclic process. A simple, general proof is presented for the case of macroscopic sources of work. Next the setup is generalized towards situations, where the corresponding work-source is not macroscopic. It is shown that using such a source one can extract energy from an equilibrium system by means of a cyclic process. However, this extraction is accompanied by an entropy increase of the source, in a manner resembling the Clausius inequality.