Phenol-selective mass spectrometric analysis of jet fuel.
Zhu, Haoxuan;Janusson, Eric;Luo, Jingwei;Piers, James;Islam, Farhana;McGarvey, G Bryce;Oliver, Allen G;Granot, Ori;McIndoe, J Scott;
The Analyst2017Vol. 142pp. 3278-3284
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zhu2017phenolselectivethe
Abstract
Bromobenzyl compounds react selectively with phenols via the Williamson ether synthesis. An imidazolium charge-tagged bromobenzyl compound can be used to reveal phenol impurities in jet fuel by analysis via electrospray ionization mass spectrometry. The complex matrix as revealed by Cold EI GC/MS analysis is reduced to a few simple sets of compounds in the charge-tagged ESI mass spectrum, primarily substituted phenols and thiols. Examination of jet fuels treated by different refinery methods reveals the efficacy of these approaches in removing these contaminants.