The effects of fly ash, calcium oxide and polypropylene fiber on the physical and mechanical properties, shrinkage and cracking behaviors of alkali-activated phosphorous slag cement (AA-PS-C) were studied. The results show that replacing 10-15% phosphorous slag by fly ash and adding calcium oxide as an expansive agent reduce the shrinkage of AA-PS-C. Fly ash will increase the flexural strength, although the compressive strength will be slightly decreased, while the calcium oxide expansive agent coated with aluminum stearate will slightly shorten the setting time and reduce the strength. Adding polypropylene fiber can greatly increase the crack-resistance of AA-PS-C.