(me4n)2so4•4snph3ncs and (me2n)2co•4snph3cl - synthesis and spectroscopic studies

(me4n)2so4•4snph3ncs and (me2n)2co•4snph3cl - synthesis and spectroscopic studies

;Libasse Diop;Kochikpa A. Y. Okio
Mineralogical Magazine 2010 Vol. 11 pp. 479-482
170
diop2010scientific(me4n)2so44snph3ncs

Abstract

Two tetranuclear SnPh3 residue containing adducts have been synthesized and characterized by infrared and Mössbauer spectroscopies. The structure are both discrete, the sulphate anion and the tetramethyl NN’ urea (TMU) acting as tetracoordinating ligands, the environment around the tin IV centres being trans trigonal bipyramidal.

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