reactive nitrogen partitioning and its relationship to winter ozone events in utah

reactive nitrogen partitioning and its relationship to winter ozone events in utah

;R. J. Wild;R. J. Wild;P. M. Edwards;P. M. Edwards;P. M. Edwards;T. S. Bates;T. S. Bates;R. C. Cohen;J. A. de Gouw;J. A. de Gouw;W. P. Dubé;W. P. Dubé;J. B. Gilman;J. B. Gilman;J. Holloway;J. Holloway;J. Kercher;A. R. Koss;A. R. Koss;L. Lee;B. M. Lerner;B. M. Lerner;R. McLaren;P. K. Quinn;J. M. Roberts;J. Stutz;J. A. Thornton;P. R. Veres;P. R. Veres;C. Warneke;C. Warneke;E. Williams;C. J. Young;C. J. Young;C. J. Young;B. Yuan;B. Yuan;K. J. Zarzana;K. J. Zarzana;S. S. Brown;S. S. Brown
Journal of agricultural and food chemistry 2016 Vol. 16 pp. 573-583
259
wild2016atmosphericreactive

Abstract

High wintertime ozone levels have been observed in the Uintah Basin, Utah, a sparsely populated rural region with intensive oil and gas operations. The reactive nitrogen budget plays an important role in tropospheric ozone formation. Measurements were taken during three field campaigns in the winters of 2012, 2013 and 2014, which experienced varying climatic conditions. Average concentrations of ozone and total reactive nitrogen were observed to be 2.5 times higher in 2013 than 2012, with 2014 an intermediate year in most respects. However, photochemically active NOx (NO + NO2) remained remarkably similar all three years. Nitric acid comprised roughly half of NOz ( ≡  NOy − NOx) in 2013, with nighttime nitric acid formation through heterogeneous uptake of N2O5 contributing approximately 6 times more than daytime formation. In 2012, N2O5 and ClNO2 were larger components of NOz relative to HNO3. The nighttime N2O5 lifetime between the high-ozone year 2013 and the low-ozone year 2012 is lower by a factor of 2.6, and much of this is due to higher aerosol surface area in the high-ozone year of 2013. A box-model simulation supports the importance of nighttime chemistry on the reactive nitrogen budget, showing a large sensitivity of NOx and ozone concentrations to nighttime processes.

Citation

ID: 147773
Ref Key: wild2016atmosphericreactive
Use this key to autocite in SciMatic or Thesis Manager

References

Blockchain Verification

Account:
NFT Contract Address:
0x95644003c57E6F55A65596E3D9Eac6813e3566dA
Article ID:
147773
Unique Identifier:
10.5194/acp-16-573-2016
Network:
Scimatic Chain (ID: 481)
Loading...
Blockchain Readiness Checklist
Authors
Abstract
Journal Name
Year
Title
5/5
Creates 1,000,000 NFT tokens for this article
Token Features:
  • ERC-1155 Standard NFT
  • 1 Million Supply per Article
  • Transferable via MetaMask
  • Permanent Blockchain Record
Blockchain QR Code
Scan with Saymatik Web3.0 Wallet

Saymatik Web3.0 Wallet