Excited-State Chemistry: Photocatalytic Methanol Oxidation by Uranyl@Zeolite through Oxygen-Centered Radicals
Li Y;Zhang G;Eugen Schwarz WH;Li J;;
Inorganic chemistry2020Vol. 59pp. -
191
y2020inorganicexcited-state
Abstract
We have elucidated the complex reaction network of partial methanol oxidation, H3COH + O2 → H2CO + H2O2, at a visible-light-activated actinide photocatalyst. The reaction inertness of C-H bonds and O═O diradicals at ambient conditions is overcom …