New Horizons in Chemical Functionalization of Endohedral Metallofullerenes

New Horizons in Chemical Functionalization of Endohedral Metallofullerenes

Michio Yamada;Michael T. H. Liu;Shigeru Nagase;Takeshi Akasaka;Yamada, Michio;Liu, Michael T. H.;Nagase, Shigeru;Akasaka, Takeshi;
molecules 2020 Vol. 25 pp. 3626-
259
yamada2020moleculesnew

Abstract

This overview explains some new aspects of chemical functionalization of endohedral metallofullerenes (EMFs) that have been unveiled in recent years. After differences in chemical reactivity between EMFs and the corresponding empty fullerenes are discussed, cage-opening reactions of EMFs are examined. Then, the selective bisfunctionalization of EMFs is explained. Finally, single-bonding derivatization of EMFs is addressed. The diversity and applicability of the chemical functionalization of endohedral metallofullerenes are presented to readers worldwide.

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111924
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10.3390/molecules25163626
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