A flexible, self-floating WO/carbon foam composite is fabricated by calcining melamine foam with WO as an adsorbate in N atmosphere. This self-floating property is simply realized by a carbonization process other than the complicated surface modification process. The simple synthesis procedure helps to increase not only the solar absorption but also the retention of WO in the porous net structure. This composite absorbs almost the whole solar spectrum and generates localized heat at the surface, which is beneficial for water evaporation. Its water evaporation rate is 6.6 times higher than that of pure water. It has a stable cyclic performance over ten cycles under the illumination of simulated sunlight (500 W Xe lamp). Its flexibility makes it easy to reuse and transfer, which is evaluated by the bending deformation test. The WO/carbon foam composite is a prospective material in solar energy conversion field, and the preparation procedure is feasible to scale-up.