Relative Stability of cis- and trans-Hydrindanones

Relative Stability of cis- and trans-Hydrindanones

Tori, Motoo;
molecules 2015 Vol. 20 pp. 1509-1518
329
tori2015relativemolecules

Abstract

The relative stabilities of several cis- and trans-hydrindanones were compared using both isomerization experiments and MM2 calculations. The generally believed rule that cis-hydrindanones are more stable than trans-isomers is applicable, but is not always true. This review introduces examples, mainly from studies in our laboratory, to explain these facts.

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