Copper(I)-BINOL Catalyzed Domino Synthesis of 1,4-Benzoxathiines through ?(????)-O Bond Formation
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Copper(I)-BINOL Catalyzed Domino Synthesis of 1,4-Benzoxathiines through ?(????)-O Bond Formation

Korupalli, Chiranjeevi;Dandapat, Arpan;Prasad, D. J. C.;Sekar, Govindasamy;Korupalli, Chiranjeevi;Dandapat, Arpan;Prasad, D. J. C.;Sekar, Govindasamy;
organic chemistry international 2011 Vol. 2011
180
chiranjeevi2011copperibinolorganic

Abstract

1,4-benzoxathiine moieties can be synthesized by domino SN2 ring opening of epoxide with o-halothiophenols followed by the copper(I)-BINOL catalyzed Ullmann-type coupling cyclization (intramolecular C(aryl)-O bond formation) with moderate to good yields.

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DOI:
10.1155/2011/980765
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https://www.hindawi.com/journals/oci/2011/980765/a...

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ID: 10993
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